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1 article(s) from Fischer, Sebastian Nils

Assembly of synthetic Aβ miniamyloids on polyol templates

Sebastian Nils Fischer and
Armin Geyer

Beilstein J. Org. Chem. 2015, 11, 2646–2653, doi:10.3762/bjoc.11.284

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Graphical Abstract

Figure 1: a) Schematic representation of the Aβ fibril formation. The monomeric peptide is shown as a colored...

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Figure 2: a) Peptide boronic acids 1 and 2 are schematically shown as green sticks (peptide) with a red gripp...

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Figure 3: Meso-erythritol is a promiscuous polyol which forms mixtures of esters due to the formation of 5-me...

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Figure 4: Diol 5 (6.08 mg, 20.0 μmol, 1.0 equiv) and 3-(acetylamino)phenylboronic acid (6, 3.56 mg, 20.0 μmol...

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Figure 5: Fmoc-Hot=Tap-OH (8).

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Figure 6: Template 9 and boronic acid 6 can form the monoesters 10 and 11, or the diester 12. The signal assi...

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Figure 7: Template 9 (2.30 mg, 4.40 µmol, 1.0 equiv) and peptide boronic acid 1 (7.35 mg, 8.80 µmol, 2.0 equi...

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Figure 8: Template 5 (¹H NMR expansion shown for reference DMSO-d₆, 300 K) and peptide Leu-Val-Phe-Phe-Ala ar...

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Figure 9: The trimeric template 16 together with 3 equivalents of pentapeptide LVFFA and 2-formylphenylboroni...

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Published 17 Dec 2015

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